PDA modified MOF-808 was introduced into SPEEK to obtain the hybrid membrane. • PDA layer on MOF-808 enhanced the vanadium resistance and interface bonding strength. • Hybrid membrane exhibited improved proton conductivity and mechanical strength. •
Porous-Nafion/PBI composite membranes and Nafion/PBI blend membranes for vanadium redox flow batteries Appl. Surf. Sci., 450 ( 2018 ), pp. 301 - 311 View PDF View article View in Scopus Google Scholar
The vanadium flow battery (VFB) as one kind of energy storage technique that has enormous impact on the stabilization and smooth output of renewable energy. Key materials like membranes, electrode, and electrolytes will finally determine the performance of VFBs. In this Perspective, we report on the current understanding of VFBs from …
Vanadium flow batteries (VFBs) are considered ideal for grid-scale, long-duration energy storage applications owing to their decoupled output power and storage capacity, high safety, efficiency, and long cycle life. However, the widespread adoption of VFBs is hindered by the use of expensive Nafion membranes. Herein, we report a soft …
A novel polybenzimidazole (PBI)-based trilayer membrane assembly is developed for application in vanadium redox flow battery (VRFB). The membrane comprises a 1 µm thin cross-linked poly[2,2′-(p-oxydiphenylene)−5,5′-bibenzimidazole] (OPBI) sandwiched between two 20 µm thick porous OPBI membranes (p-OPBI) without …
A novel oxidized black phosphorus nanosheet (O-bPn) is proposed to improve ion selectivity of sulfonated poly (ether ether ketone) (SPEEK) membrane for vanadium redox flow battery (VRFB). O-bPn possesses a unique two-dimensional (2D) puckered lattice structure, which could function as an effective blocker for vanadium ion …
The membrane is a key component of the vanadium redox flow battery (VRFB) in terms of electrochemical performance as well as costs. The standard material Nafion ® is cost intensive and therefore several alternative materials are in …
In brief One challenge in decarbonizing the power grid is developing a device that can store energy from intermittent clean energy sources such as solar and wind generators. Now, MIT researchers have …
where R 1 and R 2 are the battery''s high frequency resistances installing and uninstalling a membrane, respectively, and S is the effective area of the membrane.2.3.2 VO 2+ permeabilityThe permeability of vanadium ions was measured by using a lab self-made ...
Vanadium redox flow batteries (VRFB) are one of the emerging energy storage techniques being developed with the purpose of effectively storing renewable …
A novel polybenzimidazole (PBI)-based trilayer membrane assembly is developed for application in vanadium redox flow battery (VRFB). The membrane …
The time dependence of V (IV) ions concentration in MgSO 4 solution is illustrated in Fig. 3 is clear that the vanadium ions diffusion through the N212 is considerably faster than those diffusion through the S/P/P membrane. The permeability of VO 2+ across the S/P/P membrane and the permeability of VO 2+ across the N212 are …
Herein, novel N-alkylated and N-benzylated meta-polybenzimidazole (m-PBI) membranes are used to understand the molecular requirements of the polymer …
Vanadium redox flow batteries (VRFB) are one of the emerging energy storage techniques being developed with the purpose of effectively storing renewable energy. There are currently a limited number of papers published addressing the design considerations of the VRFB, the limitations of each component and what has been/is …
1. IntroductionThe vanadium redox battery (VRB) is based on the use of two fully soluble redox couples that are electrochemically oxidised and reduced at inert electrodes [1], [2], [3], [4].The two half-cell electrolytes are separated by an ion selective membrane. The ...
Several side-chain-type AEMs have been synthesized for exploring the effect of the chemical architecture on the performance and degradation mechanism in the vanadium flow battery (VFB). The side-chain-type AEMs having PTA groups (PSf-c-PTA) showed higher area resistance (0.6 Ω cm2) but lower vanadium permeab
Energy storage systems are considered one of the key components for the large-scale utilization of renewable energy, which usually has an intermittent nature for production. In this case, vanadium redox flow batteries (VRFBs) have emerged as one of the most promising electrochemical energy storage systems fo
Economics of vanadium redox flow battery membranes J. Power Sources, 286 (2015), pp. 247-257 View PDF View article View in Scopus Google Scholar [29] T. Mohammadi, M. Skyllas-Kazacos Evaluation of the chemical stability of some membranes in, 27 () ...
Vanadium redox flow batteries (VRFB) are a promising technology for large-scale storage of electrical energy, combining safety, high capacity, ease of …
Semantic Scholar extracted view of "Study on the Polyamine Thin Film Composite Membrane for Vanadium Battery" by Xiangguo Teng et al. DOI: 10.6023/a23080375 Corpus ID: 267468272 Study on the Polyamine Thin …
To analyze the influence of deprotonation of imidazole ring on the membrane, we investigated the membrane structure difference between Normal PBI, DP-PBI, and their derivative membranes (the membranes after subsequent treatments are denoted by the suffix –H 2 O for water treatment, and the suffix –H + for treatment with 3 …
The vanadium redox flow battery is considered the most promising candidate for large-scale electrical energy storage. The membrane, as key component, …
As a critical component of VFBs, an ICM should prevent multivalent vanadium ions in electrolytes from cross-mixing while transporting protons. The ideal ICMs should have high proton conductivity, low vanadium permeation, good chemical stability, and low cost [7,8].].
As one of the most promising large-scale energy storage systems, vanadium redox flow battery (VRFB) has attracted great attention in recent times. …
A β-cyclodextrin (β-CD) based template method is proposed for fabricating high performance nanoporous anion exchange membranes for vanadium flow batteries (VFBs). The β-CD template can be uniformly dispersed in hydroxyl modified polysulfone precursor membrane with a low degree of quaternization; removal of the template will …
A novel low-cost nanoporous polytetrafluoroethylene (PTFE)/silica composite separator has been prepared and evaluated for its use in an all-vanadium redox flow battery (VRB). The separator consists of silica particles enmeshed in a PTFE fibril matrix. It possesses ...
Modified Nafion Membrane in Vanadium Redox Flow Battery Yang Haoling, Xu Kunyu, Zhang Qi, Tao Liang, Yang Zihao, Dong Zhaoxia Progress in Chemistry ›› 2023, Vol. 35 ›› Issue (11): 1595-1612. PDF(14003 KB) Progress in Chemistry About journal ...
Vanadium flow battery (VFB) is one of the most promising candidates for large-scale energy storage. A modified polyacrylonitrile (PAN) porous membrane is successfully applied in VFB. Herein, a simple solvent post-processing method is presented to modify PAN porous membranes prepared by the traditional nonsolvent induced phase …
The trade-off between proton conduction and vanadium permeability is a great challenge for ion conductive membrane to achieve high vanadium redox flow battery (VRFB) performance. Herein, the quinone convertible phenolic hydroxyl group side chain is proposed to endow Donnan effect and continuously narrow ion conductive channel to …
2.5.4. Permeability rate of vanadium ions. A two-compartment cell was used to determine the permeability rate of vanadium ions in various oxidation states. The experimental procedure was followed as reported in the literature. 28 The increase in concentration of vanadium ions on the permeate side was determined by withdrawing samples at regular …
The membrane, as one of the key components in vanadium flow battery, plays an important role in battery performances and cost. In this paper, a series of new blend membranes based on polybenzimidazole …
The performance of a vanadium flow battery with no-gap architecture was significantly improved via several techniques. Specifically, gains arising from variation of the overall electrode thickness, membrane thickness, and …
membranes have been first modified by a polydopamine (PDA) coating and then investigated as an ion exchange membrane for a vanadium redox flow battery (VRFB). The SEM results showed that the PDA film was successfully coated on the ...
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